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Physical Properties of Minerals>
Although we have discussed x-ray identification of minerals and later in
the course will discuss techniques that can be used to identify minerals
with the optical microscope, it is still necessary to develop techniques
that can be used in the laboratory and field where instrumentation like
x-ray diffractometers or microscopes cannot be easily used. Minerals
have distinguishing physical properties that in most cases can be used to
determine the identity of the mineral. In this course, you will
develop a systematic approach to using the physical properties of minerals
as identifying tools. If you follow this approach you should be able
to identify most of the common minerals, or at the least be able to narrow
the possibilities to only a few. We will first discuss each of the
physical properties that can be used, then develop a methodical approach
to the identification of minerals using these physical properties.
Among the properties we will discuss are: crystal habit, cleavage,
hardness, density, luster, streak, color, tenacity, magnetism, and taste.
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Crystal Habit
In nature perfect crystals are rare. The faces that develop on a
crystal depend on the space available for the crystals to grow. If
crystals grow into one another or in a restricted environment, it is
possible that no well-formed crystal faces will be developed.
However, crystals sometimes develop certain forms more commonly than
others, although the symmetry may not be readily apparent from these
common forms. The term used to describe general shape of a crystal
is habit.
Some common crystal habits are as follows (discussed previously):
Individual Crystals
- Cubic - cube shapes
- Octahedral - shaped like octahedrons, as described
above.
- Tabular - rectangular shapes.
- Equant - a term used to describe
minerals that have all of their boundaries of approximately equal
length.
- Acicular - long, slender
crystals.
- Prismatic - abundance of prism
faces.
- Bladed - like a wedge or knife
blade.
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Groups of Distinct Crystals
- Dendritic - tree-like growths.
- Reticulated - lattice-like groups of
slender crystals.
- Radiated - radiating groups of
crystals.
- Fibrous - elongated clusters of
fibers.
- Botryoidal - smooth bulbous or globular
shapes.
- Globular - radiating individual
crystals that form spherical groups.
- Drusy - small crystals that cover a
surface.
- Stellated - radiating individuals that
form a star-like shape.
Some minerals characteristically show one or more of these habits, so
habit can sometimes be a powerful diagnostic tool.
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Cleavage, Parting, and Fracture
Cleavage
Crystals often contain planes of atoms along which the bonding between the atoms is weaker than along other planes. In such a case, if the mineral is struck with a hard object, it will tend to break along these planes. This property of breaking along specific planes is termed cleavage. Because cleavage occurs along planes in the crystal lattice, it can be described in the same manner that crystal forms are described. For example if a mineral has cleavage along {100} it will break easily along planes parallel to the (100) crystal face, and any other planes that are related to it by symmetry. Thus, if the mineral belongs to the tetragonal crystal system it should also cleave along faces parallel to (010), because (100) and (010) are symmetrically related by the 4-fold rotation axis. The mineral will be said to have two directions of cleavage. [Note that in the tetragonal system, the form {100} has four faces: (100), (00), (010), and (00). But if we are referring to cleavage directions, the mineral only has two, because the cleavage planes (00) and (00) are parallel to, and thus in the same direction as (010) and (100).]
The cleavage can also be described in terms of its quality, i.e., if it cleaves along perfect planes it is said to be perfect, and if it cleaves along poorly defined planes it is said to be poor.
Note: Please do not attempt to cleave the minerals in the laboratory. Many of the specimens you examine cannot be readily replaced. Cleavage is usually induced in the mineral when it is extracted from the rock when it is found, and can usually be seen as planes running through the mineral. Therefore, you do not have to break the mineral in order to see its cleavage
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Cleavage
can also be described by general forms names, for example if the mineral
breaks into rectangular shaped pieces it is said to have cubic cleavage,
if it breaks into prismatic shapes, it is said to have prismatic cleavage,
or if it breaks along basal pinacoids it is said to have pinacoidal
cleavage. For examples, see figure 2.12 on page 29 of your text.
Parting
Parting
is also a plane of weakness in the crystal structure, but it is along
planes that are weakened by some applied force. It therefore may not
be apparent in all specimens of the same mineral, but may appear if the
mineral has been subjected to the right stress conditions.
Fracture
If
the mineral contains no planes of weakness, it will break along random
directions called fracture. Several different kinds of fracture
patterns are observed.
- Conchoidal
fracture - breaks along smooth curved surfaces.
- Fibrous
and splintery - similar to the way wood breaks.
- Hackly
- jagged fractures with sharp edges.
- Uneven
or Irregular - rough irregular surfaces.
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Hardness
Hardness is determined by scratching the mineral with a mineral or substance of known hardness. Hardness is a relative scale, thus to determine a mineral's hardness, you must determine that a substance with a hardness greater than the mineral does indeed scratch the unknown mineral, and that the unknown mineral scratches a known mineral of lesser hardness.
Hardness is determined on the basis of Moh's relative scale of hardness exhibited by some common minerals. These minerals are listed below, along with the hardness of some common objects
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| Hardness |
Mineral |
Common
Objects |
| 1 |
Talc |
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| 2 |
Gypsum |
Fingernail (2+) |
| 3 |
Calcite |
Copper Penny (3+) |
| 4 |
Fluorite |
|
| 5 |
Apatite |
Steel knife blade (5+), Window glass (5.5) |
| 6 |
Orthoclase |
Steel file |
| 7 |
Quartz |
|
| 8 |
Topaz |
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| 9 |
Corundum |
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| 10 |
Diamond |
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Several
precautions are necessary for performing the hardness test.
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If
you attempt to scratch a soft mineral on the surface of a harder
mineral some of the softer substance may leave a mark of fine powder
on the harder mineral. This should not be mistaken for a scratch
on the harder mineral. A powder will easily rub off, but a
scratch will occur as a permanent indentation on the scratched
mineral.
-
Some
minerals have surfaces that are altered to a different substance that
may be softer than the original mineral. A scratch in this
softer alteration product will not reflect the true hardness of the
mineral. Always use a fresh surface to perform the hardness
test.
-
Sometimes
the habit of the mineral will make a difference. For example
aggregates of minerals may break apart leaving the impression that the
mineral is soft. Or, minerals that show fibrous or splintery habit
may break easily into fibers or splinters. It is therefore wise
to always perform the hardness test in reverse. If one mineral
appears to scratch another mineral, make sure that the other mineral
does not scratch the apparently harder mineral before you declare
which of the minerals is harder.
-
In
some minerals hardness is very dependant on direction, since hardness
is a vectorial property. When there is significant difference in
hardness in different directions, it can be a very diagnostic property
of the mineral. It is thus wise to perform the hardness test by
attempting to scratch the mineral in different directions. Two
minerals of note have differences in hardness depending on direction:
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Kyanite
has a hardness of 5 parallel to the length of the crystal, and a
hardness of 7 when scratched along a direction perpendicular to
the length.
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Calcite
has a hardness of 3 for all surfaces except the {0001}
plane. On {0001} it has a hardness of 2.
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Tenacity
Tenacity is the resistance of a mineral to breaking,
crushing, or bending. Tenacity can be described by the following
terms.
-
Brittle - Breaks or powders easily.
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Malleable - can be hammered into thin sheets.
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Sectile - can be cut into thin shavings with a
knife.
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Ductile - bends easily and does not return to
its original shape.
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Flexible - bends somewhat and does not return
to its original shape.
-
Elastic - bends but does return to its original
shape.
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Density (Specific Gravity)
Density
refers to the mass per unit volume.
Specific Gravity is the relative density, (weight of substance divided by
the weight of an equal volume of water). In cgs units density is
grams per cm3, and since water has a density of 1 g/cm3,
specific gravity would have the same numerical value has density, but no
units (units would cancel). Specific gravity is often a very
diagnostic property for those minerals that have high specific
gravities. In general, if a mineral has higher atomic number cations
it has a higher specific gravity. For example, in the carbonate
minerals the following is observed:
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| Mineral |
Composition |
Atomic # of Cation |
Specific Gravity |
| Aragonite |
CaCO3 |
40.08 |
2.94 |
| Strontianite |
SrCO3 |
87.82 |
3.78 |
| Witherite |
BaCO3 |
137.34 |
4.31 |
| Cerussite |
PbCO3 |
207.19 |
6.58 |
| Specific gravity can usually be qualitatively measured by the heft of a
mineral, in other words those with high specific gravities usually feel
heavier. Most common silicate minerals have a specific gravity
between about 2.5 and 3.0. These would feel light compared to
minerals with high specific gravities.
For comparison, examine the following table: |
| Mineral |
Composition |
Specific Gravity |
| Graphite |
C |
2.23 |
| Quartz |
SiO2 |
2.65 |
| Feldspars |
(K,Na)AlSi3O8 |
2.6 - 2.75 |
| Fluorite |
CaF2 |
3.18 |
| Topaz |
Al2SiO4(F,OH)2 |
3.53 |
| Corundum |
Al2O3 |
4.02 |
| Barite |
BaSO4 |
4.45 |
| Pyrite |
FeS2 |
5.02 |
| Galena |
PbS |
7.5 |
| Cinnabar |
HgS |
8.1 |
| Copper |
Cu |
8.9 |
| Silver |
Ag |
10.5 |
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Color
Color
is sometimes an extremely diagnostic property of a mineral, for example
olivine and epidote are almost always green in color.
But, for some minerals it is not at all diagnostic because minerals
can take on a variety of colors. For
example quartz can be clear, white, black, pink, blue, or purple.
Read in your textbook, pp. 234-240, about what causes minerals to
have color.
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Streak
Streak
is the color produced by a fine powder of the mineral when scratched on a
streak plate. Often it is
different than the color of the mineral in non- powdered form
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Luster
Luster
refers to the general appearance of a mineral surface to reflected light. Two general types of luster are designated as follows:
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Metallic
- looks shiny like a metal. Usually opaque and gives black or
dark colored streak.
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Non-metallic
- Non metallic
lusters are referred to as
-
vitreous
- looks glassy - examples: clear quartz, tourmaline
-
resinous
- looks resinous - examples: sphalerite, sulfur.
-
pearly
- iridescent pearl-like - example: apophyllite.
-
greasy
- appears to be covered with a thin layer of oil - example:
nepheline.
-
silky
- looks fibrous. - examples - some gypsum, serpentine, malachite.
-
adamantine
- brilliant luster like diamond.
Play of Colors
Interference of light reflected from the surface or from
within a mineral may cause the color of the mineral to change as the angle
of incident light changes. This sometimes gives the mineral an
iridescent quality. Minerals that show this include: bornite (Cu5FeS4)
, hematite (Fe2O3), sphalerite (ZnS), and some
specimens of labradorite (plagioclase).
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Fluorescence and Phosphorescence
Minerals that light up when exposed to ultraviolet light,
x-rays, or cathode rays are called fluorescent. If the emission of
light continues after the light is cut off, they are said to be
phosphorescent.
Some specimens of the same mineral show fluorescence while
other don't. For example some crystals of fluorite (CaF2)
show fluorescence and others do not. Other minerals show
fluorescence frequently, but not always. These include - scheelite
(CaWO4), willemite (Zn2SiO4), calcite
(CaCO3), scapolite (3NaAlSi3O8.(NaCl -
CaCO3), and diamond (C).
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Magnetism
Magnetic minerals result from
properties that are specific to a number of elements. Minerals that do not
have these elements, and thus have no magnetism are called diamagnetic.
Examples of diamagnetic minerals are quartz, plagioclase, calcite, and
apatite. Elements like Ti, Cr, V, Mn, Fe, Co, Ni, and Cu can
sometimes result in magnetism.
Minerals that contain these elements may be weakly magnetic and can be
separated from each other by their various degrees of magnetic
susceptibility. These are called paramagnetic
minerals. Paramagnetic minerals only show magnetic properties when
subjected to an external magnetic field. When the magnetic field is
removed, the minerals have no magnetism. |
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Ferromagnetic
minerals have permanent magnetism if the temperature is below the Curie
Temperature. These materials will become magnetized when
placed in a magnetic field, and will remain magnetic after the external
field is removed. Examples of such minerals are magnetite, hematite-ilmenite
solid solutions (Fe2O3 - FeTiO3), and
pyrrhotite (Fe1-xS). Other
Properties
Other
properties that may be diagnostic include chatoyancy,
asterism, piezoelectricity, and taste. Familiarize yourself
with the meanings of these terms. And
watch for these properties as you examine minerals. |
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Tables for Identification of Minerals
Beginning on page 604 of your textbook is a table of determinative
tables which should aid you in using physical properties of minerals to
identify them. Note that the tables are broken first into two
different groups based on Luster. Within each group, the minerals
are then further divided on the basis of streak, hardness, and
cleavage. In the remarks column are listed other useful diagnostic
property for each mineral. Again, I encourage you to develop a
systematic approach to identifying minerals.
Luster - Metallic or Submetallic
- Hardness < 2½
- Hardness > 2½. <5½.
- Hardness > 5½.
Luster - Nonmetallic
- Streak Colored
- Streak Colorless
- Hardness < 2½
- Hardness >2½, < 3
- Cleavage prominent.
- Cleavage not prominent.
- Hardness >3, <5½.
- Cleavage prominent.
- Cleavage not prominent.
- Hardness >5½, <7
- Cleavage prominent.
- Cleavage not prominent.
- Hardness >7
- Cleavage prominent
- Cleavage not prominent.
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